介孔分子筛表面功能膜的制备及对水体中铅汞镉的去除作用

表面改性;功能膜材料;重金属;吸附;介孔分子筛表面功能膜的制备及对水体中铅汞镉的去除作用     

手性双胺双膦-铱体系催化芳香酮的高对映选择性氢转移氢化

在异丙醇溶液中,从[Ir(COD)Cl]2和C2-对称的手性双胺双膦配体原位制备了手性能-Ir(Ⅰ)配合物,并直接用于催化几种芳香酮的不对称氢转移氢化。结果表明,该配合物是异丙基苯基酮不对称转移氢化的优秀催化剂,当底物酮与催化剂的摩尔比(S/C)为1200:1时,在室温下反应4h后,得到相应的手性芳香醇的转化率和对映选择性分别高达98%和98%ee.     

星体稳定性的维里定理

讨论了星体构型稳定性的重要性,推导了星体处于流体静力学平衡状态下的维里定理,这对定性地理解星体稳定性是很有用的。     

脊状表面减阻特性的风洞试验研究

利用热线风速仪,对光滑表面和多个脊状表面在低速风洞中进行了表面流场测试。基于测得的边界层速度分布数据,利用对数律区速度分布公式,编程分别计算出光滑表面和脊状表面的壁面摩擦速度和虚拟原点。研究发现,脊状表面最大减阻量达13．5％;有减阻效果的脊状表面使边界层速度曲线上移、湍流强度下降;与光滑表面相比,脊状表面的位移厚度和动量损失厚度明显减小,也表明脊状表面具有减阻效果;位移厚度和动量损失厚度减少量随槽间距s^＋的增加呈现先变大后变小的趋势,在S^＋=12时达到最大。     

影响SI-GaAs单晶抛光片均匀性的因素研究

高度PL mapping均匀的SI-GaAs单晶抛光片是制作大功率微波器件和大规模超高速数字集成电路的理想衬底.本工作对影响SI-GaAs单晶抛光片均匀性的各种因素进行了研究.发现位错密度对晶体的宏观电阻率均匀性和微观均匀性以及PL mapping均匀性都有一定的影响;而晶体的AB-EPD和抛光工艺对PL mapping均匀性影响更大,AB-EPD与热处理工艺有关.对实验现象进行了解释.     

Research on the hysteresis properties of unsteady aerodynamics about the oscillating wings

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绕振动机翼非定常气动力迟滞特性的模拟研究

利用数值模拟方法开展了机翼在不同条件下,由于俯仰振动引起的非定常气动力迟滞特性的模拟计算研究.根据有限体积方法对非定常欧拉方程进行数值求解,以确定相应问题的流场及气动力特性;同时,分别以具有NACA-0012翼型的矩形机翼和带有65°后掠角的三角翼为例,研究了机翼绕不同转轴或以不同频率振动的非定常气动力迟滞特性.     

Numerical discussions on complete empirical correlation in Langtry''s transition model

Recently, introducing a transition predicting model into the Reynolds averaged Navier-Stokes (RANS) environment has been paid more and more attention. Langtry proposed a correlation-based transition model in 2006, which was built strictly on local variables. However, two core correlations in the model had not been published until 2009. In this paper, after considerable analyses and discussions of the mechanism of this transition model and a series of numerical validations in the skin friction coefficient of flat plate boundary layers, a new correlation based on free-stream turbulence intensity is developed, and the empirical correlation of the transition onset momentum thickness Reynold number aiming at the hypersonic transition is improved. Low-speed/transonic airfoils and a hypersonic double wedge flat are tested to prove the reliability and practicability of this correlation.     

Numerical discussions on complete empirical correlation in Langtry＇s transition model

Recently, introducing a transition predicting model into the Reynolds averaged Navier-Stokes （RANS） environment has been paid more and more attention. Langtry proposed a correlation-based transition model in 2006, which was built strictly on local variables. However, two core correlations in the model had not been published until 2009. In this paper, after considerable analyses and discussions of the mechanism of this transition model and a series of numerical validations in the skin friction coefficient of flat plate boundary layers, a new correlation based on free-stream turbulence intensity is developed, and the empirical correlation of the transition onset momentum thickness Reynold number aiming at the hypersonic transition is improved. Low-speed/transonic airfoils and a hypersonic double wedge fiat are tested to prove the reliability and practicability of this correlation.     

特殊形貌CdSe纳米晶的制备*

CdSe纳米晶是II-VI族半导体中研究最多的材料之一,由于其发射波长随纳米晶的尺寸而改变,从而可以覆盖从绿到红的宽光谱范围,因此CdSe纳米晶可以应用于生物标记和荧光显示等领域,各种制备CdSe纳米晶的方法也应运而生。因制备方法的不同,所得CdSe纳米晶的粒径、相结构及形貌也不同,进而影响CdSe纳米晶的性质。本文归纳了7种典型的制备一些特殊形貌的CdSe纳米晶的最新方法,并对各种方法的优缺点作了简单评价。最后,对这一领域未来的研究和发展方向作了展望。